Photocatalytic Degradation of a Congo red Using ZnO/rutile-$TiO_2$, ZnO, rutile-$TiO_2$ and CdS
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2001, v.14 no.3, pp.259-265
Kim, Chang Suk
Ryu, Hae-Ill
Kim,
C. S., &
Ryu,
H.
(2001). Photocatalytic Degradation of a Congo red Using ZnO/rutile-<TEX>$TiO_2$</TEX>, ZnO, rutile-<TEX>$TiO_2$</TEX> and CdS. , 14(3), 259-265.
Abstract
Photocatalytic degradation of Congo red was performed using various semiconductors as ZnO, CdS, rutile-$TiO_2$ or mixed rutile-$TiO_2$/ZnO. The change of degradation of the dye was investigated by UV-visible spectrophotometric method. The photocatalytic action of CdS was greater than ZnO and rutile-$TiO_2$ in account of low band gap energy of CdS. The rate of photocatalytic degradation reaction increased drastically in according to increasing ratio of ZnO on mixed rutile-$TiO_2$/ZnO. These photocatalytic effect of rutile-$TiO_2$ was suppressed by more stable rutile-$TiO_2$, doping the hydrolysis product with $Zn^{2+}$ prior to calcination onto the rutile-$TiO_2$ surface.
- keywords
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photocatalytic,
Congo red,
semiconductro,
absorbance