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  • P-ISSN1225-0163
  • E-ISSN2288-8985
  • SCOPUS, ESCI, KCI

Article Detail

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  • P-ISSN 1225-0163
  • E-ISSN 2288-8985

Article Contents

    Preparatin of Ag, Pd, and Pt50-Ru50 colloids prerared by r-irradiation and electron beam and electrochemical immobilization on gold surface

    Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
    2006, v.19 no.4, pp.333-341







    A.Gopalan

    Abstract

    PVP-protected Ag, Pd and $Pt_{50}-Ru_{50}$ colloids were prepared independently by using ${\gamma}$-irradiation and electron beam (EB) at ambient temperature. UV-visible spectra of these colloids show the characteristic bands of surface resonance and give evidence for the formation of nanoparticles. Transmission electron microscopy (TEM) experiments were used to know the morphology of nanoparticles prepared by ${\gamma}$-irradiation and EB. The size of Ag, Pd, and $Pt_{50}-Ru_{50}$ nanoparticles prepared by ${\gamma}$-irradiation was ca. 13, 2-3, 15 nm, respectively. While, the size of Ag, Pd, and $Pt_{50}-Ru_{50}$ nanoparticles prepared by EB was ca. 10, 6, and 1-3 nm, respectively. Cyclic voltamograms (CV) were recorded for the Au electrodes immobilized with these nanoparticles. CVs indicated the modifications in the surface as a result of immobilization.

    keywords
    <TEX>${\gamma}$</TEX>-Irradiation, Electron beam, Ag colloids, Pd colloids, <TEX>$Pt_{50}-Ru_{50}$</TEX> colloids, Cyclic voltammetry

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