- P-ISSN 1225-0163
- E-ISSN 2288-8985
- P-ISSN1225-0163
- E-ISSN2288-8985
- SCOPUS, ESCI, KCI
Article Detail
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Preparation and characterization of prospective disulfide based electrode materials ofr lithium batteries
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2008, v.21 no.1, pp.25-33
Dhanusuraman,
R.
, Anantha,
I.
, &
(2008). Preparation and characterization of prospective disulfide based electrode materials ofr lithium batteries. , 21(1), 25-33.
Abstract
Organic disulfide compounds are having higher theoretical capacity than the conventional cathodematerial and are considered as the important storage material. Here, we are reporting the preparation of poly(2,2'-dithiodianiline) PDDA/multiwall carbon nanotubes, (MWCNTs) composites under different experimentalof composites. Composites were prepared in the presence of cetyl trimethyl bromide (CTAB), a cationicsurfactant, and also in the absence of CTAB. A physical mixture of PDTDA and MWCNTs was formed withunfunctionalized MWCNTs. Grafting of PDDA onto MWCNTs was performed by chemical oxidative polymerizationof 2, 2-dithiodianiline in the presence of amine functionalized MWCNTs. The composites of MWCNTs andPDTDA were characterized for structure, morphology anspectroscopy, Fourier transform Raman spectroscopy, scanning electron microscopy and UV-visible spectroscopy.The composite materials prepared by this method are expected to find applications as electrode materials forlithium batteries.
- keywords
- 2, 2'-dithiodianiline, chemical oxidative polymerization, cathode materials
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