<TEX>$({\eta}^5-C_5Me_5)_2BiCl$</TEX>, The First Organobismuth Compound with <TEX>$\pi$</TEX>-bonded Cyclopentadienyl Ring Analysized by X-ray Diffractometry

Lorberth, J.; Shin, Sung-Hee; 신성희; Kong, Young Kun; 공영건

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P-ISSN1225-0163
E-ISSN2288-8985
SCOPUS, ESCI, KCI

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P-ISSN 1225-0163
E-ISSN 2288-8985

e-Submission

Vol.11, No.1

PubReader Citation

$({\eta}^5-C_5Me_5)_2BiCl$, The First Organobismuth Compound with $\pi$-bonded Cyclopentadienyl Ring Analysized by X-ray Diffractometry

Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985

1998, v.11 no.1, pp.42-46

Lorberth, J.
Shin, Sung-Hee
Kong, Young Kun

Lorberth, J., Shin, S., & Kong, Y. K. (1998). <TEX>$({\eta}^5-C_5Me_5)_2BiCl$</TEX>, The First Organobismuth Compound with <TEX>$\pi$</TEX>-bonded Cyclopentadienyl Ring Analysized by X-ray Diffractometry. , 11(1), 42-46.

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Abstract

The reaction of $({\eta}^5-C_5Me_5)_2K$ with $BiCl_3$ yielded $({\eta}^5-C_5Me_5)_2BiCl$[I], the first organobismuth compound with ${\pi}$-bonded cyclopentadienyl ring. The compound I which was the violet crystal (yield, 30%) was decomposed to $PCpBiCl_2$. The Structure of $({\eta}^5-C_5Me_5)_2BiCl$ was identified as single crystal by X-ray diffraction method. The eliminated product $C_{20}H_{30}$, triclinic crystal of space group p1(Z