Synthesis and Characterization of 2,2'-Biimidazole

Collier, Harvest L.; 콜리어 하배스트; Cho, Il Young; 조일영

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P-ISSN1225-0163
E-ISSN2288-8985
SCOPUS, ESCI, KCI

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P-ISSN 1225-0163
E-ISSN 2288-8985

e-Submission

Vol.11, No.1

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Synthesis and Characterization of 2,2'-Biimidazole

Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985

1998, v.11 no.1, pp.8-12

Collier, Harvest L.
Cho, Il Young

Collier, H. L., & Cho, I. Y. (1998). Synthesis and Characterization of 2,2'-Biimidazole. , 11(1), 8-12.

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Abstract

The 2,2'-Biimidazole was synthesized by the reaction between glycol and ammonium solution. The correct solid structure of 2,2'-biimidazole in this method reported either trans ($C_{2h}$) or cis ($C_{2v}$) form. In this study, the correct structure of 2,2'-biimidazole was analysed by both FTIR and Raman spectroscopy using mutual exclusion properties of them. Also, it was analysed by $^1H$ and $^{13}C$ NMR and computer molecular modeling. The structure of 2,2'-biimidazole found to be trans ($C_{2h}$) than cis ($C_{2v}$) by comparison between FTIR and Raman Spectra. This results agree with computer molecular modeling and x-ray crystallography. This study provide good evidence for identifying structural orientation of the 2,2'-biimidazole containing pyridyl nitrogen.