Synthesis, Protonation Constants and Stability Constants for Transition Metal ions(II) of 1, 15-Bis(2-Hydroxybenzyl)-2, 6, 10, 14-Tetraazapentadecane

Kim, Sun-Deuk; 김선덕; Kim, Jun-Kwang; 김준광; Lee, Woo-Sik; 이우식

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P-ISSN1225-0163
E-ISSN2288-8985
SCOPUS, ESCI, KCI

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P-ISSN 1225-0163
E-ISSN 2288-8985

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13권 6호

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1, 15-Bis(2-Hydroxybenzyl)-2, 6, 10, 14-Tetraazapentadecane 리간드합성, 양성자 해리상수 및 전이금속에 대한 안정도 상수결정

Synthesis, Protonation Constants and Stability Constants for Transition Metal ions(II) of 1, 15-Bis(2-Hydroxybenzyl)-2, 6, 10, 14-Tetraazapentadecane

분석과학 / Analytical Science and Technology, (P)1225-0163; (E)2288-8985

2000, v.13 no.6, pp.810-814

김선덕
김준광
이우식

김선덕, 김준광, & 이우식. (2000). 1, 15-Bis(2-Hydroxybenzyl)-2, 6, 10, 14-Tetraazapentadecane 리간드합성, 양성자 해리상수 및 전이금속에 대한 안정도 상수결정. , 13(6), 810-814.

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Abstract

The open-chain hexadentate $N_4$, $O_2$ ligands 1, 15-bis(2-hydroxybenzyl)-2, 6, 10, 14-tetraazapentadecane (BSATPD. 4HCl) has been synthesized as its tetrahydro-chloride salt and characterized by EA, IR, NMR, and Mass spectrum. Its protonation constants ($logK_n{^H}$) and stability constants ($logK_{ML}$) for $Cu^{2+}$, $Ni^{2+}$, $Co^{2+}$ and $Zn^{2+}$ ions were determined in aqueous solution by potentiometry and compared with those of analogous $N_4$, $O_2$ ligands contain ethtylenic spacers or propylenic spacers, which make six-membered chelate rings between the aliphatic nitrogen atoms.

keywords: ligand, potentiometry, stability constants

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1, 15-Bis(2-Hydroxybenzyl)-2, 6, 10, 14-Tetraazapentadecane 리간드합성, 양성자 해리상수 및 전이금속에 대한 안정도 상수결정

Synthesis, Protonation Constants and Stability Constants for Transition Metal ions(II) of 1, 15-Bis(2-Hydroxybenzyl)-2, 6, 10, 14-Tetraazapentadecane

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