The Study on the Mechanism for Oxidation Reaction of Boratabenzne by Cyclic Voltammetry

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P-ISSN1225-0163
E-ISSN2288-8985
SCOPUS, ESCI, KCI

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P-ISSN 1225-0163
E-ISSN 2288-8985

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Vol.15, No.6

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The Study on the Mechanism for Oxidation Reaction of Boratabenzne by Cyclic Voltammetry

Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985

2002, v.15 no.6, pp.550-555

(2002). The Study on the Mechanism for Oxidation Reaction of Boratabenzne by Cyclic Voltammetry. , 15(6), 550-555.

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Abstract

The oxidation mechanism of boratabenzene was studied. As a model compound the ferrocene analogue (${\eta}^6$-1-Methylboratabenzene)(${\eta}^5$-Pentamethylcyclopentadiennyl)iron 3 was chosen. The complex underwent irreversible oxidation in the presence of ortho proton on the ring and a methyl group on the boron atom in methanol medium. Chemical oxidations with $Hg(OAc)_2$, $HgSO_4$, $Cu(OH)_2$, $AgCF_3SO_3$ or $FeCl_3$ in MeOH gave, via a transition state [3], at first the derivates 6 and 7, which were converted to each 8 and 9.